Bazı sikloalkollerle hekzaklorosiklotrifosfazenin reaksiyonlarının incelenmesi / Investigation of the reaction of hexachlorocyclotriphosphazene with some cycloalcohols

Abstract

Siklohekzanol, 3-Metil siklohekzanol, 4- Metil siklohekzanol, Siklopentanol ve Siklopropil metanol'ün oda sıcaklığında, argon atmosferinde ve THF ortamında Na ile alkolatları oluşturuldu. Bu alkolatlar ile hekzaklorosiklotrifosfazen[(NPCl2)3](I) oda sıcaklığında, argon atmosferinde, THF ortamında reaksiyonlarından tam sübstitüe hekza(siklohekzoksi)siklotrifosfazen(II), Hekza(3-metil siklohekzoksi)silkotrifosfazen (III) Hekza(4-metil siklohekzoksi) silkotrifosfazen (IV), Hekza(siklopentoksi)siklotrifosfazen(V) ve Hekza(siklopropilmetoksi)siklotrifosfazen(VI) bileşikleri sentezlendi. Bileşiklerin yapıları IR, (1H, 13C, 31P) NMR spektroskopisi yöntemi ile aydınlatıldı. ANAHTAR KELİMELER: Fosfazenler, siklotrtifosfazenler, organofosfazen, hekzaklorosiklotrifosfazen. The alcoholats were carried out by the reactions of sodium with cyclohexyl alcohol, 3-methyl cyclohexyl alcohol, 4-methyl cyclohexyl alcohol, cyclopenthyl alcohol and cyclopropyl emthyl alcohol in THF solvent at room temperature under argon atmosphere. The reactions of these alcoholats with hekzacholorocyclotriphosphazene were performed in THF solvent at room temperature. Fully substituted hexa(cyclohexyloxy)cyclotriphosphazene(II), hexa(3-methyl cyclohexyloxy)cyclotriphosphazene(III), hexa(4-methyl cyclohexyloxy)cyclotriphosphazene(IV), hexa(cyclopentyloxy)cyclotriphosphazene(V) and hexa(cyclopropylmethyloxy)cyclotriphosphazene (VI) in these reactions were isolated. The structures of the compounds were characterized by 1H, 13C and 31P NMR spectroscopy, infrared and elemental analysis. KEY WORDS: Phosphazenes, cyclotriphosphazenes, organophosphazene, hexachlorocyclotriphosphazene