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DC Field | Value | Language |
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dc.contributor.author | KOÇ, MEHMET | - |
dc.date.accessioned | 2019-08-01T06:23:05Z | - |
dc.date.available | 2019-08-01T06:23:05Z | - |
dc.date.issued | 2016 | - |
dc.identifier.uri | http://hdl.handle.net/11513/1352 | - |
dc.description.abstract | Bu çalışmamızda, hekzaklorosiklotrifosfazen ile 3 M'lık dietil eterdeki ve 1 M'lık THF'deki fenilmagnezyum bromürün tepkimesinden yüksek verimde hekzafenilsiklotrifosfazen sentezlemek için en iyi tepkime şartları belirlendi. Tepkimeler toluen çözücünde oda şartlarında Ar atmosferinde gerçekleştirildi. Grignard bileşikleri 6.6, 12 ve 24 eşdeğere karşılık hacimde kullanıldı. tepkimelerin hepsi beş gün devam ettirildi. En yüksek verimde hekzafenilsiklotrifosfazen dietil eterdeki fenilmagnezyum bromürden elde edildi. Elde edilen bileşiğin yapısı IR, NMR ve elementel analiz yöntemleriyle karakterize edildi. ANAHTAR KELİMELER: Fosfazen, siklotrtifosfazen, organofosfazen, Grignard, organomet This our study, the best reaction conditions were determined for hexaphenylcyclotriphosphazene in high yield from the reaction of hexachlorocyclotriphosphazene[(NPCl2)3](I) with phenylmagnesiumbromide in 3 M diethyl ethere and 1M THF solution. All reactions were carried out in toluene solvent under Ar atmosphere at room conditions. The Grignard reagent were used in a volume corresponding 6.6, 12 and 24 equivalent. Each reaction was continued for five days. The highest yield hexaphenylcyclotriphosphazene was obtained form phenylmagnesiumbromide in diethylethere solution. The structure of the compound was determined by IR and NMR spectroscopy. KEY WORDS: Phosphazene, cyclotriphosphazenes, organophosphazene, Grignard, organometallic | en_US |
dc.language.iso | tr | en_US |
dc.subject | Kimya = Chemistry | en_US |
dc.title | Hekzaklorosiklotrifosfazen ile fenilmagnezyum bromürün tepkimesinden iyi verimde organosiklotrifozfazen elde etmek için tepkime şartlarının belirlenmesi / The determination of reaction conditions for organocyclotriphosphazenes in high yield from reaction of hexachlorocyclotriphosphazene with phenylmagnesium bromide | en_US |
dc.type | Thesis | en_US |
Appears in Collections: | Fen Bilimleri Enstitüsü |
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444118.pdf | 482.21 kB | Adobe PDF | View/Open |
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